Anisaldehyde Schiff base from

Dwivedi, B. K. et al., Indian J. Chem., 1987, 26A, 618—620 Twelve tris-complexes [Sn(C104)2.3L] between tin(II) perchlorate and Schiff bases derived from salicylaldehyde, anisaldehyde, or 2-hydroxy-1 -naphthaldehyde and aromatic amines were investigated for thermal instability. 

The reactions of CpTiCl3 with 4-amino-3-mercapto-6-methyl-5-oxo-l,2,4-triazine and its Schiff bases (derived from benzaldehyde, 2-chlorobenzaldehyde, anisaldehyde, salicylaldehyde, 2-hydroxynaphthaldehyde, and 2-hydroxyace-tophenone) have been studied in THF and CH2G12 in the absence and presence of amine in different molar ratios.997... 

TiX4,n(3-cyanopyridine) (X = Cl or Br and n = 1 or 2) complexes have been prepared from their constituent molecules by mixing in a chlorinated hydrocarbon solvent. I.r. spectra suggest that, for the n = 2 complexes, the ligands are co-ordinated via the pyridine nitrogen only, but that when n — 1 the cyano-nitrogen is also involved. The complexes TiCl4L2 have been characterized, where L is a unidentate, aromatic Schiff base derived from benzaldehyde, anisaldehyde, or salicylaldehyde and amines such as aniline, 0-, m-, or p-toluidine or other substituted anilines. The electronic and i.r. spectra of these complexes are consistent with octahedral stereochemistry... 

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