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Anilidate, to protect phosphate groups

Nucleotides in aqueous solution can be alkylated at the phosphate (and in some cases the nucleoside also) by the action of l-oxidopyridin-2-yldiazo-methane (33). - The protecting group may be removed from the phosphate with snake venom phosphodiesterase, or generally by acetic anhydride treatment, followed by ammonia. Phosphoramidates have been described previously as phosphate-protecting groups, and if 2-naphthylamine is used as its anilidate for this purpose, organic solvent extraction (as above) is possible. A variation on this theme is to use dianilidophosphochloridate (34) as a... [Pg.154]


See other pages where Anilidate, to protect phosphate groups is mentioned: [Pg.185]    [Pg.63]   
See also in sourсe #XX -- [ Pg.983 ]




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5 -Phosphate group

Anilid

Anilidates, to protect phosphate groups

Anilidates, to protect phosphate groups

Anilide

Anilides

Anilids

Phosphate protecting groups

Phosphates, protection

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