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Analytical synergism

Mutual synergism of binary mixtures containing fine particles can be quantified in terms of the departure of the 0-x2 curve from a linear tie line, which signifies absence of synergism, joining 7 and 2 for the respective components, as shown in Fig. 54. A convenient measure of this departure is the shaded area lying between the -x2-curve and the linear tie line. This can be derived analytically in terms of what will be called the Synergism number Sy, normalized with respect to 07+0, of both the coarse and the fine particles ... [Pg.568]

Synergic action of receptors Is preferred for maximization of an analytical signal. A concurrent reduction of dipolar potential and molecular packing will amplify any one receptoi—stimulant complexation in comparison to singular alteration of either parameter. [Pg.359]

Compared with earlier approaches, both prospecting and exploiting of the fields is greatly aided and accelerated by advanced analytical technology and, in particular, by synergism with theoretical and computational chemistry. Overall, asymmetric organocatalysis has matured in recent few years into a very powerful, practical, and broadly applicable third methodological approach in catalytic asymmetric... [Pg.7]

There is a synergism between adsorption and chromatographic processes which is clearly demonstrated in the supercritical fluid literature. Research in supercritical fluid chromatography can usually be divided into analytical applications and the measurement of physicochemical data. Early analytical separations methodology performed at pressures close to ambient conditions... [Pg.151]

Random error can over- or underestimate risk and is generally not as severe as bias. Moreover, the magnitude of error can be estimated with statistical techniques. Assessment of confounding, synergism, or effect modification can be accomplished in the analytical phase (by stratification or multivariate modeling), providing sufficient data have been collected on those factors. Restriction or randomization procedures also can be used in the design phase to minimize confounders. [Pg.230]

Synergism caused by the addition of Group C particles was found from both SEM microscopy and video macroscopy (Xia and Kwauk, 1985) to be associated with adhesion of these line particles on the coarse particle. Nevertheless, more appropriate analytical, or even theoretical, ground needs to be found to account for the initial rise and later fall in the value of the dimensionless time 0 as the mass fraction of fines increases from zero to unity. [Pg.260]

A biosensor is a synergic combination of analytical biochemistry and microelectronics. Biosensors have recently been considered as a highly potential field of scientific research. This is because development of biosensors is necessary for the realisation of implantable, integrated and intelligent devices for biochemical information [17]. Biosensors are analytical devices that respond selectively to analytes in a given sample and convert their... [Pg.298]

III)/multiwalled carbon nanotubes (Fe P/MWCNTs) composites showed well-enough resolved peaks to allow the simultaneous analyses of ascorbic acid, dopamine, uric acid, and nitrite in urine and serum samples [186]. This result was assigned to the 71-interaction between the analytes and MWCNT, as well as the synergic effects of Fe "P and MWCNTs. [Pg.55]


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