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Analysis of LPS Current Maxima

EPS voltammetry employing a linear potential scan j = vt is a widely applied technique. The theoretical basis of this method was elaborated for different [Pg.83]

1) Such case is possible in the Au Au(I) CN system containing no extra cyanide (see Section 8.1.3). [Pg.83]

In this case, the position of current peak does not depend on v, that is, Ep = const. If the reduction process is irreversible, the latter relationship undergoes a change [10]  [Pg.84]

More complicated dependencies arise when a slow chemical step precedes the charge transfer. To compare the ip of the reversible redox process with i produced by slow first-order chemical reaction, the empiric relation was suggested (see [11])  [Pg.84]

Techniques Based on the Control of the Intensity of Forced Convection [Pg.85]


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