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Amphiphilic 2 rotaxane

The squaraine rotaxane tetracarboxylic acid 15a is soluble in aqueous solution at physiological pH and acts as an excellent fluorescent marker with extremely high photostability, which allows trafficking processes in cells to be monitored in realtime, with constant sample illumination, over many minutes. This type of real-time monitoring cannot be done with other available NIR fluorescent probes, such as the amphiphilic styryl dye KM4-64 and water-soluble dextran-Alexa 647 conjugate, because they are rapidly photobleached. [Pg.171]

Fig. 8.7 Chemical switching of an amphiphilic bistable [2]rotaxane 64+ in a condensed phase, monitored by X-ray photoelectron spectroscopy. Fig. 8.7 Chemical switching of an amphiphilic bistable [2]rotaxane 64+ in a condensed phase, monitored by X-ray photoelectron spectroscopy.
Over the past decade, cycIo6w(paraquat-p-phenylene) has been the benchmark compound in the design of molecular switches, in 7t-7t-stacking, and related dynamic processes and this continues in redox-controllable amphiphilic [2]rotaxanes <04CEJ155>. [Pg.420]

Amphiphilic Single-station Rotaxane-based Devices... [Pg.10]

A Slow Amphiphilic Bistable Rotaxane-based Device... [Pg.15]

Fig. 1.17 Proposed electromechanical mechanism for the operation of the device based on the amphiphilic, bistable [2]rotaxane 13" ". ... Fig. 1.17 Proposed electromechanical mechanism for the operation of the device based on the amphiphilic, bistable [2]rotaxane 13" ". ...
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See also in sourсe #XX -- [ Pg.147 ]



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