2- Aminophenyl phenyl sulfide

An unprecedented [3,5]-rearrangement was reported to be involved in the conversion of -(arylthio)acylhydrazoncs 154 into 4-aminophenyl phenyl sulfide 155238 (equation 60). Some other rearrangements of arylhydrazones resulting in indole239 and triazole derivatives240 as well as in 3-azapyranosic A - ary 1 am in olac tarn s241 are also noteworthy. 

B is( -butylthio)benzene and 1,4-bis( -butylthio)benzene have been prepared from the corresponding dibromobenzene and cuprous w-butylmercaptide, using a mixture of quinoline and pyridine as solvent.6, l,2-Bis(phenylthio)benzene and 1,4-bis(phenylthio)benzenehave been prepared from the corresponding dichloro- or dibromobenzenes and cuprous phenylmercaptide, using a mixture of quinoline and pyridine as solvent.5 1,4-Bis(phenylthio)benzene has also been prepared from -dibromo-benzene or -bromophenyl phenyl sulfide and lead phenylmercaptide 7 and from diazotized 4-aminophenyl phenyl sulfide and sodium phenylmercaptide.8... 

A series of alkyl sulfides react with phenyl azide in TFA and TFSA to produce 2- and 4-aminophenyl alkyl sulfides 120 and 121 (Scheme 52). Kinetics results appeared to rule out Sn2 reactions, and the ortho-product... 

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