Aminoadamantane

Chemical Name 1-adamantanamine hydrochloride Common Name 1-aminoadamantane hydrochloride Structural Formula nh ... 

After cooling, the solution was diluted with 1.5 liters of water and subjected to three extractions with ether. The amine was extracted from the ethereal solution with 2 N HCI and liberated therefrom by the addition of solid NaOH (while cooling). The alkaline solution was extracted with ether and the ethereal solution was dried with soiid NaOH. Distii-lation resulted in 10.6 grams (70% of the theory) of 1-aminoadamantane which, after sublimation, melted at 180° to 192°C (seal capillary). It is converted to the hydrochloride. 

Tertiary amines have been oxidized to the corresponding nitro compounds with KMn04. For example, 2-methyl-2-nitropropane is prepared in 84% yield from t-butylamine with KMn04 (Eq. 2.55).117 In a similar fashion, 1-aminoadamantane has been oxidized to 1-nitroadamantane in 85% yield with KMn04 (see Eq. 2.63).118... 

Complexes of 1-boraadamantane with 1-aminoadamantane were found to possess antiviral <1996CHEC-II(8)889> and antihepatitis C activity <2003JME2823>. 

Aminoacetaldehyde diethyl acetal, d306 Aminoacetaldehyde dimethyl acetal, d506 1-Aminoadamantane, a64 Aminoanisoles, m48 thru m50 / -Aminoazobenzene, p88... 

B Gustavsson, I Betner. Fully automated amino acid analysis for protein and peptide hydrolysates by precolumn derivatization with 9-fluorenylmethylchloroformate and 1-aminoadamantane. J Chromatogr 507 67-77, 1990. 

Aminoacetaldehyde dimethyl acetal, d440 1-Aminoadamantane, a66 Aminoanisoles, m42, m43, m44 p- Aminoazobenzene, p87... 

DDR Deca-dodecasil 3R [Sii20O240]- R. R = 1 -aminoadamantane Sigma-1 (Si02/Al203 60)... 

This procedure and, importantly, the force fields used to describe the zeolite-template interactions in the atom-atom approximation, have been well validated against experiments. Firstly, the locations of a number of templates within zeolites have been determined by single crystal or powder X-ray diffraction. Thus, for example, the templates 1-aminoadamantane and N-methylquinuclidinium cation have been used to crystallize the LEV... 

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