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Amines metal complexes, bridging

Numerous dinucleating macrocyclic and macrobicyclic ligands have been synthesized, in particular by the versatile amine + carbonyl — imine reaction they form dinuclear metal complexes as well as cascade complexes with bridging groups [2.58-2.63, 3.24-3.27, 4.1-4.4], for instance in dicobalt complexes that are oxygen carriers [3.26]. [Pg.39]

Kim aud coworkers explored a known receptor 2,6-bis(bis(2-pyridylmethyl)aminomelhyl)-4-meihyl-phenol (H-bpmp) for naked-eye detection of phosphate anion in aqueous solution." Zn + coordination with bis(2-picolyl)amine (Dpa) together with the formation of a phenoxo-bridged dinuclear metal complex (32) affords the anion binding pocket The pH-sensitive dye pyrocatechol violet (8) was chosen as the indicator for the competition assay. When [Zn2(H-bpmp)] + was titrated into a solution of 8 at pH 7.0, the solution color changed from yellow (444 nm) to blue... [Pg.136]


See other pages where Amines metal complexes, bridging is mentioned: [Pg.165]    [Pg.1075]    [Pg.1087]    [Pg.121]    [Pg.156]    [Pg.256]    [Pg.94]    [Pg.237]    [Pg.376]    [Pg.157]    [Pg.101]    [Pg.290]    [Pg.94]    [Pg.170]    [Pg.290]    [Pg.261]    [Pg.107]    [Pg.939]    [Pg.2107]    [Pg.2365]    [Pg.3719]    [Pg.253]    [Pg.379]    [Pg.380]    [Pg.381]    [Pg.145]    [Pg.143]    [Pg.153]    [Pg.156]    [Pg.227]    [Pg.329]    [Pg.117]    [Pg.963]    [Pg.155]    [Pg.2106]    [Pg.2364]    [Pg.3718]    [Pg.240]    [Pg.166]    [Pg.381]    [Pg.194]    [Pg.150]    [Pg.500]    [Pg.341]    [Pg.153]    [Pg.225]    [Pg.23]    [Pg.1048]    [Pg.397]   
See also in sourсe #XX -- [ Pg.2 , Pg.496 ]




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Amines complexes

Amines metal complexes

Amines metallation

Metal bridged

Metal-amine

Metalation amines

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