Amidines nitroso compounds

Horner synthesis with nitroso compounds Amidines... 

An equimolar amount of methanolic 10%-KOH added with stirring and Dry Ice-acetone cooling at -40° to a soln. of diphenyl a-anilino-p-nitrobenzylphospho-nate in tetrahydrofuran, then 2-pyridinecarboxaldehyde in tetrahydrofuran added product. Y ca. 100%. F. e., also amidines from nitroso compounds, s. H. Zimmer and J. P. Bercz, A. 686, 107 (1965). 

From To — Akanes CycJoaikanes Akenes Akynes Aryls Halogen compounds Alcohols Phenols Ethers, Quinones B, 5 and Si compounds P and BI compounds Nttro. Nitroso, Azo. Azoxy, Hydrazo Azides Amines Organometahic compounds Adehydes Ketones Acids. AnHyd rides. Esters Amides, Amidines. Nitriles Hydroxy-aldehydes or -ketones. Sugars. Hydroxy acids Ammo acids. Peptides Heterocycles Nucleosides Miscellaneous, including heterocycles... 

---

See also in sourсe #XX -- [ ]

---