Aluminum single crystal structures

The X-ray single crystal structures of two discrete aluminum-(salen) catalysts were established as mentioned in Section 6.1. 

We begin with the structure of a noble metal catalyst. The emphasis is on the preparation of rhodium on aluminum oxide and the nature of the metal-support interaction. Next we focus on a promoted surface in a review of potassium on noble metals. This section illustrates how single crystal techniques have been applied to investigate to what extent promoters perturb the surface of a catalyst. The third study deals with the sulfidic cobalt-molybdenum catalysts used in hydrotreating reactions. Here we are concerned with the composition and structure of the catalytically active... 

An opposing effect is possible under the severe conditions of a single extraction with HC1 some of the aluminum removed from the crystal structure may not be transported out of the catalyst particle. The resulting amorphous alumina, (after subsequent calcining) remaining in the particle would cause some reduction in effective diffusivity. Such amorphous alumina has been suggested by others (17,18). 

The silicon detectors were made of n-typed single crystal of 1 mm thick. They have a MOS structure of gold, tungsten oxide, n-typed silicon and aluminum back contact. Since these layers can be deposited on the silicon wafer by evaporation techniques, the fabrication process is so simple as to be applicable to fabrication of the detectors for a special use. No surface treatment for passivation is given to them so that their performance is affected by ambient gases. For example, some good detectors show a leakage current of half micro-ampere at room temperature in the atmosphere, but a few micro-ampere in vacuum. So, in order to stabilize their performance, the silicon detectors were operated at the dry ice temterature. 

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