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Aluminum hydride, diisobutyl- DIBAL pyridines

Numerous procedures have been reported for the synthesis of iV-protected-a-amino aldehydes [78]. The A-protected a-amino aldehydes can be prepared either by oxidation of the corresponding A-protected j8-amino alcohols with oxidants such as pyridinium dichromate [79,80] or SOs-pyridine-di-methyl sulfoxide (DMSO) [81] or under Swem conditions [DMSO-oxalyl chloride-A,A-diisopropylethylamine (DIEA)] [81-83], by reduction of esters with diisobutyl aluminum hydride (DIBAL) [84], by reduction of A,A-disubstituted amides [85-87], by reduction of urethane-protected A-carboxy-... [Pg.651]


See also in sourсe #XX -- [ Pg.584 ]

See also in sourсe #XX -- [ Pg.8 , Pg.584 ]

See also in sourсe #XX -- [ Pg.8 , Pg.584 ]




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Dibal

Diisobutyl

Diisobutyl aluminum

Diisobutyl aluminum hydride

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