Aluminum-Carbonyl Complexation, Activation, and Nucleophilic Reaction

2 Aluminum-Carbonyl Complexation, Activation, and Nucleophilic Reaction Pericyclic Reaction and Asymmetric Reaction 

Pericyclic addition reactions are attractive C-C, C-N, and C-O bond-formation reactions for many reasons. They involve  

Synthetically more readily availability of aluminum chemistry in pericyclic reaction was made possible, in particular, by Yamamoto and coworkers, who showed that the steric bulk of aluminum reagents is synthetically strategic, facilitating unprecedented selectivity and reactivity. 

The exo-selectivity was more apparent when using ATPH although a characteris- 

Novel stereoselectivity in tandem inter[4+2]/intra[3+2] nitroalkene cycloaddition 

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