Aluminates redistribution

Red-Al s. Sodium dihydridobis-(2-methoxyethoxo)aluminate Redistribution s. Disproportionation Redoxcondensation -, review 24, 413s31 Reducing scents... 

Red-Al s. Sodium dihydridobis-(2-methoxyethoxo)aluminate Redistribution s. Disproportionation Redox. s. a. Ring closure, redoxidative Redoxcondensation -, review 24, 413s31 Redox conditions, reactions of oximes under - 32, 129 Redoxidation of nitro compds. 32, 242... 

The replacement of vanadia-based catalysts in the reduction of NOx with ammonia is of interest due to the toxicity of vanadium. Tentative investigations on the use of noble metals in the NO + NH3 reaction have been nicely reviewed by Bosch and Janssen [85], More recently, Seker et al. [86] did not completely succeed on Pt/Al203 with a significant formation of N20 according to the temperature and the water composition. Moreover, 25 ppm S02 has a detrimental effect on the selectivity with selectivity towards the oxidation of NH3 into NO enhanced above 300°C. Supported copper-based catalysts have shown to exhibit excellent activity for NOx abatement. Recently Suarez et al and Blanco et al. [87,88] reported high performances of Cu0/Ni0-Al203 monolithic catalysts with NO/NOz = 1 at low temperature. Different oxidic copper species have been previously identified in those catalytic systems with Cu2+, copper aluminate and CuO species [89], Subsequent additions of Ni2+ in octahedral sites of subsurface layers induce a redistribution of Cu2+ with a surface copper enrichment. Such redistribution... 

In such complex system as aluminosilicate precursor gels, various lifetime components can appear reflecting material structure. The gel structure is a result of direct interaction of cations with silicate, aluminate and aluminosilicate anions, redistribution of charges and electron density over the system of aluminosiloxane bonds with effect on the formation of different structural units [24],... 

Subsurface contamination by uranium wastes and contaminant speciation during transport from a wastewater pond (originating from a plutonium production plant) to groundwater were studied by Catalano et al. (2006). Land disposal of basic sodium aluminates and acidic U(VI)-Cn(ll) and their redistribution in the vadose zone resulted in development of a groundwater nraninm plume. The solid phase speciation of nraninm from the base of the pond, throngh the subsurface, to the... 

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