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Allyltin compounds substitution reactions

The two principal routes to the organotin peroxides involve substitution by a peroxide nucleophile at a tin centre (equations 14-69 and 14-70), or (pericyclic) reaction of an allyltin compound with singlet oxygen (equation 14-71). Distannyl peroxides have also been prepared by the (homolytic) reaction of distannanes with triplet oxygen (equation 14-72). [Pg.234]

Driven by the inability to substitute allyltin compounds at the 3-position, Keck examined intermolecular addition reactions of allyl sulfides [50]. He was able to show that 3-methyl- and 3,3-dimethyl-substituted allyl phenyl sulfides 86 and 88 undergo reaction with alkyl halides and alkyl phenyl selenides in the presence of hexabutylditin to form good yields of the allylation products (Scheme 18). These... [Pg.62]

In basic aqueous media, a kinetic study of the reaction between stannate(II) ions and alkyl halide shows that mono- and disubstituted organotin compounds are formed (Eq. 6.12a).27 The monosubstituted organotin compound is obtained after a nucleophilic substitution catalyzed by a complexation between the tin(II) and the halide atom. The disubstituted compound results from an electrophilic substitution coupled with a redox reaction on a complex between the monosubstituted organotin compound and the stannate(II) ion. Stannate(IV) ions prevent the synthesis of the disubstituted compound by complexation. Similarly, when allyl bromide and tin were stirred in D2O at 60° C, allyltin(II) bromide was formed first. This was followed by further reaction with another molecule of allyl bromide to give diallyltin(IV) dibromide (Eq. 6.12b).28... [Pg.175]


See other pages where Allyltin compounds substitution reactions is mentioned: [Pg.54]    [Pg.1336]    [Pg.1336]    [Pg.745]    [Pg.106]    [Pg.357]    [Pg.605]    [Pg.832]    [Pg.832]   
See also in sourсe #XX -- [ Pg.1382 ]

See also in sourсe #XX -- [ Pg.1382 ]




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Allyltin

Allyltin compounds

Allyltin substituted

Substituted Compounds

Substitution compounds

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