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Allyl methacrylate solution polymerization

Procedure 6-1 is an example of the solution polymerization of allyl methacrylate using benzoyl peroxide as initiator. The polymer is said to be thermoplastic. [Pg.306]

Allyl group containing polymers have been found to cross-link readily on e-beam exposure. Free radical solution polymerization of allyl methacrylate has been shown to result in a unique polymer with about 65% pendant allyl groups and the remainder believed to be involved in a cyclization propagation step. The exact structure of this polymer has yet to be established however, it differs significantly in physical properties from anionically prepared poly(allyl methacrylate), which has a structure with 100% pendant allyl groups. The of the former polymer is llO C, compared to the latter, which is 36 The free radically prepared polymer is very sensitive to e-beam radiation (1.5 X 10"Ccm" at lOkeV) but has poor physical properties such as adhesion, etc. Copolymerization of allyl methacrylate with glycidyl methacrylate results in copolymers with equivalent... [Pg.979]


See other pages where Allyl methacrylate solution polymerization is mentioned: [Pg.73]    [Pg.281]    [Pg.306]    [Pg.310]    [Pg.518]    [Pg.271]    [Pg.25]    [Pg.203]    [Pg.155]    [Pg.235]    [Pg.97]    [Pg.540]    [Pg.157]   
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Allyl methacrylate

Allyl methacrylate, polymerization

Allyl polymerization

Allylic polymerization

Methacrylate polymerization

Methacrylates, polymerization

Methacrylic polymerization

Polymeric methacrylates

Polymeric solutions

Polymerization solution polymerizations

Solution polymerization

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