Allyl Complexes of Palladium and Platinum

Allyl Complexes of Palladium and Platinum. A preliminary report has appeared on the structure of one of thediastereoisomersof ( -methylallyl)-(2 it,5 a-(phenylethylimino-3-penten-4 1ato)palladium(n) (92). ThePd-C 

The unusual structure of the dimeric [ Pd(ir-CaH5)a 2Ci,H,oNOH] complex (93) involves both a bridging chlorine atom and an intramolecular 

A partial three-dimensional structure determination of [PdCl(QHgCl)]jj (94) was undertaken in order to find the point of attachment of the chlorine 

Bis(acac-/i-allyl-platinum) (95) contains bridging allyl groups, each of which forms a a-bond to one metal atom and a w-bond to the other. Each platinum atom is bonded to two oxygen atoms, a carbon atom, and an 

In [Pd2(CsH5)I(PPh3)2] (96) there is a linear P-Pd-Pd-P skeleton, the Pd-P and Pd-Pd distances being 2.278(15) and 2.686(7) A. The symmetrically bridging iodine atom is 2.650(4) A from both metal atoms. The brid g allyl group is disordered.  

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