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Allenyl organometallics

However, reaction of the same allenyl organometallic species with cyclohexenone generates only the four-membered ring cycloadduct (42) (equation 34). In Ae latter case it is likely that the (7i -alle-... [Pg.279]

The mechanism of the condensation between allenyl organometallics and carbonyl groups is thought to be a cyclic Se< (or 5e2 ) process. In the reaction of aldehydes with 1,2-butadienylmagnesium halides, the anti syn product ratio depends on the size of substitutent group of the aldehyde and may be rationalized as shown in (1). ... [Pg.91]

Reactions ofAllyl and Propargyl/Allenic Organometallics with Imines and Iminium Ions 993 Table IS Reaction of Propargyl/Allenyl Organometallic Reagents (59) with Imines (60 Equation 14)... [Pg.993]


See other pages where Allenyl organometallics is mentioned: [Pg.1073]    [Pg.1073]    [Pg.1075]    [Pg.1077]    [Pg.1148]    [Pg.403]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.82]    [Pg.85]    [Pg.88]    [Pg.89]    [Pg.93]    [Pg.95]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.81]    [Pg.82]    [Pg.83]    [Pg.87]    [Pg.88]    [Pg.91]    [Pg.93]    [Pg.95]    [Pg.97]   
See also in sourсe #XX -- [ Pg.2 , Pg.81 , Pg.82 , Pg.83 , Pg.84 , Pg.85 , Pg.86 , Pg.87 , Pg.88 , Pg.89 , Pg.90 , Pg.91 , Pg.92 , Pg.93 , Pg.94 , Pg.95 , Pg.96 ]

See also in sourсe #XX -- [ Pg.81 , Pg.82 , Pg.83 , Pg.84 , Pg.85 , Pg.86 , Pg.87 , Pg.88 , Pg.89 , Pg.90 , Pg.91 , Pg.92 , Pg.93 , Pg.94 , Pg.95 , Pg.96 ]

See also in sourсe #XX -- [ Pg.81 , Pg.82 , Pg.83 , Pg.84 , Pg.85 , Pg.86 , Pg.87 , Pg.88 , Pg.89 , Pg.90 , Pg.91 , Pg.92 , Pg.93 , Pg.94 , Pg.95 , Pg.96 ]

See also in sourсe #XX -- [ Pg.81 , Pg.82 , Pg.83 , Pg.84 , Pg.85 , Pg.86 , Pg.87 , Pg.88 , Pg.89 , Pg.90 , Pg.91 , Pg.92 , Pg.93 , Pg.94 , Pg.95 , Pg.96 ]




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Allenyl

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