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Allenyl chloromethyl sulfone

The cycloaddition reaction of the allenyl chloromethyl sulfone 130c was successfully applied to an iterative ring-annulation procedure [115]. [Pg.770]

Allenyl chloromethyl sulfoxide (57) reacts with m-CPBA to furnish allenyl chloromethyl sulfone (58) (eq 21). The enethi-olizahle thioketone (59) has been oxidized to the ( )-sulfine (60) (eq 22). The 2 -deoxy-4-pyrimidinone (62) has been prepared by reacting the 2-thiop3Timidine nucleoside (61) with m-CPBA (eq 23). Thioamides have been transformed to the amides in high yields. ... [Pg.91]


See other pages where Allenyl chloromethyl sulfone is mentioned: [Pg.5]    [Pg.5]    [Pg.5]    [Pg.5]   
See also in sourсe #XX -- [ Pg.5 ]




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Allenyl

Allenyl sulfone

Allenyl sulfones

Allenylation

Chloromethyl

Chloromethyl sulfones

Chloromethylated

Chloromethylation

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