Alkylative amination alkyltitanium complexes

Alkyltitanium(IV) complexes having N -dialkylamino ligand systems, RTi(NR 2)3, fail to give nucleophilic additions to carbonyl compounds (Section 1.5.3.1.1). Their reaction with aldehydes leads instead to tertiary amines by addition of both the alkyl moiety of the reagent and one of the N, -dialkylamino ligands (equation 59). The synthetic interest of the reaction is restricted to noneno-lizable aldehydes, since enolizable carbonyl compounds lead to enamines. ... 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

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