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Alkylation, mechanism with cinnamic acid

The oxidation of substituted /3-benzoylpropionic acids by PFC follows the Hammett relation with a negative reaction constant. A possible mechanism for the oxidation has been discussed.5 The oxidation of maleic, fumaric, crotonic, and cinnamic acids by PCC is of first order with respect to PCC and the acid. The oxidation rate in 19 organic solvents has been analysed by Kamlet s and Swain s multiparametric equations. A mechanism involving a three-centre transition state has been postulated.6 The relative reactivity of bishomoallylic tertiary alcohols toward PCC, to yield substituted THF products via the tethered chromate ester, is dependent only on the number of alkyl groups. This observation suggests a symmetrical transition state in this intramolecular Cr(VI)-alkene reaction.7 Mechanisms have been proposed for the oxidation of 2-nitrobenzaldehyde with PBC8 and of crotonaldehyde with tetraethylammonium chlorochromate.9... [Pg.86]

See other pages where Alkylation, mechanism with cinnamic acid is mentioned: [Pg.333]    [Pg.115]    [Pg.694]    [Pg.357]    [Pg.106]    [Pg.84]    [Pg.221]    [Pg.137]    [Pg.506]    [Pg.103]    [Pg.90]   
See also in sourсe #XX -- [ Pg.122 ]



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Acidizing mechanisms

Acids cinnamic acid

Alkyl cinnamates

Alkylation mechanism

Cinnamate

Cinnamates

Cinnamic 4-

Cinnamic acid

Cinnamic acid, alkylation with

Cinnamic acid/cinnamate

Cinnamics

Mechanisms acids

Mechanisms alkylations

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