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Alkyl perfluoro carboxylates reduction

Photochemically induced reduction of alkyl perfluoro carboxylates in hexa-methylphosphoramide (FfMPA) can replace one, two, or (in the case of tn-fluoroacetate) three a-fluonne atoms with hydrogen [7, S] (equation 5) Chlorine-containing fluorocarboxylates preferentially lose a-chlorme and may even lose P-chlorinc in preference to a fluonne [9] (equation 6) Cyclic a-fluoroketones are also defluonnated photochemically [10] (equation 7)... [Pg.298]


See other pages where Alkyl perfluoro carboxylates reduction is mentioned: [Pg.241]   
See also in sourсe #XX -- [ Pg.298 , Pg.299 ]

See also in sourсe #XX -- [ Pg.298 , Pg.299 ]

See also in sourсe #XX -- [ Pg.298 , Pg.299 ]




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Alkyl carboxylate

Alkyl carboxylates

Alkyl perfluoro carboxylates

Alkyl reduction

Carboxylate alkylation

Carboxylates alkylation

Carboxylation, reductive

Carboxylic reduction

Perfluoro-3-

Reduction alkylation

Reduction reductive alkylation

Reductive alkylation

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