Alkoxometalate chlorides

These alkoxometalate chloride derivatives, EC1XL x, can be converted into their alkoxometalate alkoxide or /3-diketonate analogues by their reaction with alkali alkoxide or /3-diketonate in the appropriate molar ratios. 

The reactions of metal chlorides with alkali metal alkoxometalates have been extensively employed (4a, 6, 7, 12, 17, 19) for the synthesis of soluble het-... 

The intermediate chloride derivatives, for example, MCI y x(LA )x(LZr)>(LTa), were also isolated in a few cases and can be converted into alkoxometalate alkoxide or other (e.g., /3-diketonate) derivatives by the following types of reactions ... 

Partially substituted products, MClj j,Lj, have been reported by the reactions of anhydrous chlorides of various metals with alkali alkoxometallates in suitable stoichiometric ratios (Eqs 3.58-3.62) ... 

Cl2Y Ti2(OPr )9 i Cl2La Zr2(OI )9 43 and ClLa Zr2(OPr )9 2. Thus the general method of synthesizing chloride alkoxometallate derivatives of different metals (M) can be easily described by the following general reaction (Eq. 3.62) with y < x ... 

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