Alkali metal polyhydrogen fluorides

Alkali metal polyhydrogen fluoride systems, MF nHF where M = K, Rb, Cs or mixtures thereof and n = 0.5 - 3 are versatile fluorination media for halogen exchange reactions. The chemical and physical properties of these systems will be discussed as well as their applicability towards fluorocarbon synthesis. [Pg.237]

FERNANDEZ AND THRASHER Alkali Metal Polyhydrogen Fluorides... [Pg.239]

Alkali metal polyhydrogen fluoride melts are tunable, participatory solvents for halogen exchange, HF addition, and HX elimination reactions. High conversions with excellent selectivities to the desired fluorocarbon products are possible with the appropriate melt. The resulting alkali metal chlorides can be easily regenerated with anhydrous hydrogen fluoride in a separate step. [Pg.248]

Addition reaction, alkali metal polyhydrogen fluorides as halogen exchange media, 240-242... [Pg.440]

Alkali metal polyhydrogen fluorides as halogen exchange media addition reaction, 240-242 concept, 237-238 previous studies, 238-239 regeneration reaction, 241-248 substitution reaction, 240-242 thermodynamics, 237-239 Alkane(s), functionalization strategies, 366 Alkane activation, 366-367 Alkenyl cadmium reagents, synthesis, 298-300... [Pg.440]

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