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Alcohols, secondary, oxidation with Oxone

Two tandem alkene metathesis-oxidation procedures using Grubb s second-generation ruthenium catalyst resulted in unique functional group transformations. Use of sodium periodate and cerium(III) chloride, in acetonitrile-water, furnished cis-diols. Oxidation with Oxone, in the presence of sodium hydrogencarbonate, yielded a-hydroxy ketones.296 Secondary alcohols are oxidized to ketones by a hydrogen... [Pg.125]

Interestingly, the reaction of a solid slurry of Oxone and wet Alumina with solutions of cyclic ketones in CH2CI2 provokes Baeyer-Villiger oxidation to give the corresponding lactones (eq 2). The same wet alumina-Oxone reagent can be used to oxidize secondary alcohols to ketones (eq 3). Aldehydes are oxidized to acids by aqueous Oxone. ... [Pg.334]

Oxone oxidizes metal complexes including tris[(2-oxazolinyl)-phenolato] manganese(III) which, in conjunction with -Bu4NBr, is an effective oxidant for aromatic and primary and secondary aliphatic alcohols. ... [Pg.338]

See other pages where Alcohols, secondary, oxidation with Oxone is mentioned: [Pg.389]    [Pg.150]    [Pg.131]    [Pg.338]    [Pg.479]    [Pg.13]    [Pg.109]    [Pg.1777]    [Pg.478]    [Pg.39]    [Pg.110]   
See also in sourсe #XX -- [ Pg.133 ]



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Alcohols secondary alcohol

Alcohols, oxidation with

Oxidation oxone

Oxonation

Oxone

Oxone®, secondary oxidant

Oxons

Secondary alcohols oxidation

Secondary oxidants

Secondary oxidation

With OXONE

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