AgClOs Silver chlorate

AgCl Silver chloride, 1 3 AgClOs Silver chlorate, 2 4 AgF Silver(I) fluoride, 4 136 AgF2 Silver (II) fluoride, 3 176 Agl Silver iodide, 2 6 AgO Silver (II) oxide, 4 12 Ag2CN2 Silver cyanamide, 1 98 Ag2P03F Silver monofluorophos-phate, 3 109... 

AgCl Silver chloride, 1 3 AgClOs Silver chlorate, 2 4 AgF Silver(I) fluoride, 4 136 6 19, 20... 

AgCl Silver chloride, 1 3 AgClOs Silver chlorate, 2 4... 

Ha.la.tes, Silver chlorate, AgClO, silver bromate, AgBrO, and silver iodate, AglO, have been prepared. The halates may decompose explosively if heated. 

A product of sufficient purity for use in the oxidation reactions mentioned above may be prepared by dissolving 170 g. (1 mol) of silver nitrate and 106 g. (1 mol) of sodium chlorate each in 100 ml. of water. After the two solutions are heated to 85°, they are mixed and allowed to cool slowly to 0°, and at this temperature the mother liquor is carefully decanted. Fifty milliliters of distUled water, previously cooled to 0°, is added to the solid product, and the crystals are separated by suction filtration. Yield 150 g. (78.5 per cent). The product contains 95.2 per cent AgClOs as indicated by a silver determination. 

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