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ADVANCED POLYMERIZATION CONCEPTS

The concept of functionaUty and its relationship to polymer formation was first advanced by Carothers (15). Flory (16) gready expanded the theoretical consideration and mathematical treatment of polycondensation systems. Thus if a dibasic acid and a diol react to form a polyester, assumiag there is no possibihty of other side reactions to compHcate the issue, only linear polymer molecules are formed. When the reactants are present ia stoichiometric amouats, the average degree of polymerization, follows the equatioa ... [Pg.35]

An important advance in ion-selective electrodes (ISEs) and related systems was based on the concept of polymeric liquid membranes developed by Eisenman [122]. The principle of this approach was to incorporate an organic compound as the ionophore into a polyvinyl chloride membrane... [Pg.585]


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