Adsorption piezometric methods

Measurement of the transient adsorption or desorption curve for a sample of zeolite crystals exposed to a step change in ambient sorbate concentration (pressure) provides, in principle, a simple and direct method of measuring the intracrystalline diffusivity (D). Such measurements are conveniently carried out by gravimetric, volumetric or piezometric methods. The... [Pg.345]

Brandani, S., Analysis of the Piezometric Method for the Stucfy of Diflusion in Microporous Solids Isothermal Case, Adsorption, 4, 17 (1998). [Pg.171]

The intracrystalline diffusivities of the hydrocarbons were measured under the conditions of the temperature range of 373-773 K and the pressure range of 0-1.33 kPa by the constant volume method [9]. The apparatus and the procedure are the same as employed by Hashimoto et al. [4,5]. Change in the total pressure caused by adsorption was recorded by use of a piezometric sensor with a transducer, the response of which is first enough to measure accurately the pressure change. To eliminate the influence of several factors (such as mass conductivity between the sorbate and the pressure sensor) on the pressure change, the blank tests were conducted without zeolites. Comparing these data obtained with those with zeolites, an uptake curve of the amount adsorbed was obtained. [Pg.478]

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