Adsorbed metalloprotein electron transfer

Sumi, H. (1998) V-I characteristics of STM processes as a probe detecting vibronic interactions at a redox state in large molecular adsorbates such as electron-transfer metalloproteins. Journal of Physical Chemistry E, 102, 1833-1844. 

By contrast, the Hg electrode has not fared well in studies of electron-transfer metalloproteins. In almost all cases, the electrochemical response has been dominated by undesirable features signals arising from adsorbed molecules, which do not reflect the accepted redox chemistry of the metal centres, and irreversible waves due to sluggish reduction and reoxidation of protein molecules in bulk solution. Nevertheless, the studies that have been made are informative and some wilt be mentioned briefly here. All potentials given in this article have been corrected to correspond with the Standard Hydrogen Electrode (SHE). 

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