Adiabatic processes Isobaric combustion

Only the ideal cases of an isothermal-isobaric combustion process will be assumed. This combustion is superior to the usual isobaric-adiabatic process. Such an assumption can be verified more easily than in a normal combustion process, since in the cases studied here the chemical reactions take place at the surface of the oxygen carriers. 

A thermodynamic quantity of considerable importance in many combustion problems is the adiabatic flame temperature. If a given combustible mixture (a closed system) at a specified initial T and p is allowed to approach chemical equilibrium by means of an isobaric, adiabatic process, then the final temperature attained by the system is the adiabatic flame temperature T. Clearly depends on the pressure, the initial temperature and the initial composition of the system. The equations governing the process are p = constant (isobaric), H = constant (adiabatic, isobaric) and the atom-conservation equations combining these with the chemical-equilibrium equations (at p, T ) determines all final conditions (and therefore, in particular, Tj). Detailed procedures for solving the governing equations to obtain Tj> are described in [17], [19], [27], and [30], for example. Essentially, a value of Tf is assumed, the atom-conservation equations and equilibrium equations are solved as indicated at the end of Section A.3, the final enthalpy is computed and compared with the initial enthalpy, and the entire process is repeated for other values of until the initial and final enthalpies agree. 

Assume a process for each of the four devices (1) compressor as adiabatic with efficiency of 85%, (2) combustion chamber as isobaric, (3) turbine as adiabatic with efficiency of 89%, and (4) heat exchanger as isobaric on both hot and cold sides. Input the given information (1) working fluid is air, (2) inlet pressure and temperature of the compression device are 14.7 psia and 60°F, (3) inlet pressure and temperature of the turbine are 120 psia and 2000°F, (4) mass flow rate of air is 1 Ibm/sec, (5) exit pressure of the turbine is 14.7 psia, (6) display the exit temperature of the compressor (it is 562.5°F), and (7) input the exit temperature of the exhaust turbine gas... 

Figure 13 shows the exergetic efficiency vs. the maximum temperature for different combustion processes with and without intermediate reactions. As a comparison, the adiabatic, isobaric... 

Inspection of the experimental results guides the modeling of the state inside the bubble. We consider several steps, see Fig.3 From Pq to pg the compression is adiabatic, then follows an isochoric combustion leading to the state Pg, Tg. On the new adiabate 3, a further compression to the maximum pressure Pg Snay take place and, finally/ the products will be expanded to p. Since at r the gas temperature will still be high, there is little condensation up to this point, especially due to the buffering effect of the inert gas component. The process will be finished by a slow isobaric cooling and condensation to the end point In this first approach, effects like radiation, heat conduction, and compressibility are neglected. 

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