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Adamantanoid cages

Decametallic complexes, 166 fused adamantanoid cages, 166 teiracapped octahedron, 166 Decarboxylation keto acids... [Pg.588]

Fig. 3.27 a The distorted adamantanoid cage in cocrystal structure of H4MTB with phenazine. b Schematic view of the sevenfold interpenetration, c The adamantanoid cage in cocrystal structure of H4MTB with dipy. d Schematic view of the 18-fold interpenetration [85]... [Pg.96]

A unique tridentate trianionic ligand derived from trimetaphosphimic acid has been reported. Reaction with M0C12(H20)8 (M = Zr, Hf) gave the isotypic complexes Na4[M4(/i4-0) (/i-0H)6(P02M I)3]4 (M = Zr (104), Hf). These clusters adopted an adamantanoid M—O cage where the trimetaphosphimato ligand chelated each of the metal centers of the [M4(/r4-0) (/r-OH)6]8+ core.564... [Pg.139]

Figure 34 Part of the crystal structure of [Cd(SC5H4-4-Me)2], showing the protrusion of 4-methyIbenzenethiolate ligands into an internal cavity surrounded by adamantanoid [Cd4( i-SAr)6(n-SAr)4/2] cages, which are symbolized by the large tetrahedra... Figure 34 Part of the crystal structure of [Cd(SC5H4-4-Me)2], showing the protrusion of 4-methyIbenzenethiolate ligands into an internal cavity surrounded by adamantanoid [Cd4( i-SAr)6(n-SAr)4/2] cages, which are symbolized by the large tetrahedra...
See other pages where Adamantanoid cages is mentioned: [Pg.78]    [Pg.120]    [Pg.208]    [Pg.151]    [Pg.564]    [Pg.471]    [Pg.530]    [Pg.168]    [Pg.166]    [Pg.580]    [Pg.212]    [Pg.212]    [Pg.213]    [Pg.208]    [Pg.1437]    [Pg.377]    [Pg.51]    [Pg.78]    [Pg.120]    [Pg.208]    [Pg.151]    [Pg.564]    [Pg.471]    [Pg.530]    [Pg.168]    [Pg.166]    [Pg.580]    [Pg.212]    [Pg.212]    [Pg.213]    [Pg.208]    [Pg.1437]    [Pg.377]    [Pg.51]    [Pg.166]    [Pg.37]    [Pg.42]    [Pg.181]    [Pg.276]    [Pg.388]    [Pg.392]   
See also in sourсe #XX -- [ Pg.151 ]

See also in sourсe #XX -- [ Pg.151 ]



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