Adamantane-Branched, Ester Connectivity

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1411 a) N. J. Turro, J. K. Barton, D. A. Tomalia, Acc. Chem. Res. 1991, 24, 332. b) Y. Li, P. L. Dubin, R. Spindler, D. A. Tomalia, Macromolecules 1995, 28, 8426 Dubin et al. have studied complex formation between carboxylated, PAMAM-type dendrimers and poly(dimethyldial-lylammonium chloride) to gain insight into colloid diameter, or surface curvature, with polyelectrolyte binding. Based on turbidity experiments, observations were consistent with those of Turro et al. 138 411 higher generation dendrimers behave as hindered Stern layer structures whereas early generations exhibit simple electrolyte characteristics.  

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