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Acyloxonium ions

FIGURE 7.6 Decomposition of a mixed anhydride (A) to the 2-alkoxy-5(4//)-oxazolone and the alkyl carbonate.9 The latter is in equilibrium with the anion whose reaction (B) with a second molecule of anhydride produces pyrocarbonate and the acid anion whose reaction (C) with a third molecule produces the symmetrical anhydride. The oxazolone eventually reacts with the alcohol to give the ester. (D) Acyloxonium ions formed by reaction of the anhydride with dimethylformamide and tetrahydrofuran. [Pg.204]

Acyloxy-group participation in carbohydrate chemistry is reported in the prceed- 4 g paper by H. Paulsen, H.Behre and C.-P. Herald Acyloxonium-Ion-Umlage-rungen in der Kohlenhydratchemie. [Pg.1]

Acyloxonium-Ion-Umlagerungen in der Kohlenhydratchemie 3. Darstellung in fliissigem Fluorwasserstoff... [Pg.113]


See other pages where Acyloxonium ions is mentioned: [Pg.95]    [Pg.139]    [Pg.26]    [Pg.29]    [Pg.41]    [Pg.55]    [Pg.236]    [Pg.329]    [Pg.339]    [Pg.200]    [Pg.229]    [Pg.229]    [Pg.203]    [Pg.36]    [Pg.49]    [Pg.106]    [Pg.107]    [Pg.109]    [Pg.111]    [Pg.115]    [Pg.117]    [Pg.119]    [Pg.121]    [Pg.123]    [Pg.125]    [Pg.127]    [Pg.131]    [Pg.137]    [Pg.139]    [Pg.141]    [Pg.142]    [Pg.143]    [Pg.144]    [Pg.145]    [Pg.147]    [Pg.149]    [Pg.151]    [Pg.153]    [Pg.155]    [Pg.157]    [Pg.9]    [Pg.296]    [Pg.527]    [Pg.528]    [Pg.96]   
See also in sourсe #XX -- [ Pg.728 ]

See also in sourсe #XX -- [ Pg.147 ]

See also in sourсe #XX -- [ Pg.14 , Pg.203 ]




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Acyloxonium Ions and Orthoesters

Acyloxonium ions, formation from

Cyclic acyloxonium ions

Paulsen, H., Cyclic Acyloxonium Ions

Rearrangement of Acyloxonium Ions in Polyol Systems

Rearrangement of acyloxonium ions

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