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Acyclic alkanes butane

Having set out the properties of tantalum and zirconium hydride toward C-H bond activation of alkanes we now describe the catalytic hydrogenolysis of C-C bonds. It was previously shown in the laboratory that supported-hydrides of group 4 metals, and particularly of zirconium, catalyze the hydrogenolysis of alkanes [21] and even polyethylene [5] into an ultimate composition of methane and ethane. However, to our initial surprise, these zirconium hydrides did not cleave ethane. (=SiO)2Ta-H also catalyzes the hydrogenolysis of acyclic alkanes such as propane, butane, isobutane and neopentane. But, unlike the group 4 metals, it can also cleave ethane [10], Figure 3.7 illustrates this difference of behavior between (=SiO)2Ta(H) and [(=SiO)(4.j,)Zr(H) ], x= or 2). With Ta, propane is completely transformed into methane by successive reactions, while with Zr only equimolar amounts of methane and ethane are obtained. [Pg.82]

In the presence of an acyclic alkane, 3 catalyzes at moderate temperature (25-200 °C) the metathesis reaction, leading to the formation of heavier and lower homolog alkanes by simultaneous breaking and formation of C-H and C-C bonds. For example, propane is transformed, even at 25 °C into a quasi-equimolar mixture of ethane and butanes (n- and iso-mixture) as well as methane and pentanes, in lower quantities. Lower and heavier homologs are also obtained starting from... [Pg.87]

Oxidation of cyclohexane with Oj can be described by a series of elementary reactions similar to the ones for n-butane. In this case, however, the hydrocarbon contains no primary hydrogens and three times as many secondary hydrogens as the acyclic alkane. Chain lengths are, therefore, longer and reaction products less numerous. Cyclohexyl hydroperoxide and cyclohexanol are the major propagation products while cyclohexanone and cyclohexanol are formed in termination ... [Pg.581]

Alkanes. The saturated open-chain (acyclic) hydrocarbons (C H2 +2) have names ending in -ane. The first four members have the trivial names methane (CH4), ethane (CH3CH3 or C2H5), propane (C3H8), and butane (C4Hjo). For the remainder of the alkanes, the first portion of the name... [Pg.1]

We have met the breaking of C—C bonds by hydrogen already in Chapter 11, but the molecules considered there (cyclopropane and cyclobutane) had some degree of alkene-like character and reacted easily (especially the former). In this chapter we shall be involved with linear and branched alkanes having two, three or four carbon atoms. C—C bond fission is the principal process, but with the butanes skeletal isomerisation is also possible, and dehydrogenation sometimes happens at the same time. Reactions of acyclic and cyclic alkanes having five or more carbon atoms feature in the following chapter, where isomerisation and dehydrocyclisation are the important reactions. Some limited overlap between this chapters and the next is unavoidable. [Pg.525]


See other pages where Acyclic alkanes butane is mentioned: [Pg.480]    [Pg.57]    [Pg.352]    [Pg.12]    [Pg.148]    [Pg.86]    [Pg.107]    [Pg.55]    [Pg.370]    [Pg.447]    [Pg.31]   
See also in sourсe #XX -- [ Pg.134 , Pg.134 , Pg.135 , Pg.136 , Pg.136 ]




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