Activation of organic molecule

Klopman, G. (1984) Artificial intelligence approach to structure-activity studies. Computer automated structure evaluation of biological activity of organic molecules. J. Am. Chem. Soc. 106, 7315-7318. 

We have previously emphasized the activation of organic molecule via coordination. The converse may also be true, such that transition metals may be used as protecting groups for reactive unsaturated functional groups. Thus t 4-metal coordination of a butadiene system deactivates it pjgure 6.27 Butadiene towards Diels-Alder reactions. Friedel-Crafts acylation of free polyenes coordination modes... 

The activation of organic molecules in a flow system operation of LCVD starts at the boundary of glow, i.e., boundary of luminous gas phase and gas phase monomer. The supply of the monomer into the luminous gas phase is a crucial factor because the monomer is consumed in the glow by depositing polymers and the numbers of polymer-forming species in the glow decreases. 

Klopman, G. (1984). Artificial Intelhgence Approach to Structure-Activities Studies. Computer Automated Structure Evaluation of Biological Activity of Organic Molecules. J.Am. Chem. Soc., 106,7315-7321. 

Pullman B, Pullman A. Electron-donor or electron-acceptor properties and carcinogenic activity of organic molecules. Nature 1963 199 467-9. 

MATRIX, a new algorithm for the prediction of biological activity of organic molecules based on multidimensional analysis of physicochemical descriptors of modern drugs 02ZOR1618. 

Many coordination chemists are concerned with enhancing the chemical reactivity and/or selectivity of metal complexes, particularly for applications in catalysis. For example, a coordinatively unsaturated cationic metal complex, which is often the intermediate implicated in activation of organic molecules, is considered. Wanted is a solvent... 

The very low conversion achieved with H-Y is likely due to the high hydro-philicity of the zeolite [10], which in the presence of a large excess of water makes the adsorption and activation of organic molecules more difficult. The H-... 

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