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Acrylamide reaction rate data

Preliminary kinetic data on the catalyzed hydrogenation of acrylamide using HRuCl(diop)2 generally show a first-order dependence on hydrogen, between a first- and a zero-order on both ruthenium and substrate, and an inverse dependence on added diop at lower substrate concentrations. These dependences are consistent with the mechanism outlined below (Reaction 4) and the corresponding rate law (Equation 5). The less than first-order dependence on ru-... [Pg.134]

FIGURE 4.6 Increase in polymerization rate by addition of reducing agent, NajSjO, to reaction initiated by K2S2OJ. Slope of log-log plot is 0.5 in either case. (Data from Riggs, J. R., The Aqueous Phase Polymerization of Acrylamide A Kinetics and Mechanism Study, PhD thesis, Cornell University Press, Ithaca, NY, 1964.)... [Pg.124]

See other pages where Acrylamide reaction rate data is mentioned: [Pg.3767]    [Pg.283]    [Pg.600]    [Pg.778]    [Pg.778]    [Pg.82]    [Pg.143]    [Pg.291]    [Pg.23]    [Pg.248]    [Pg.183]    [Pg.248]    [Pg.76]    [Pg.812]   
See also in sourсe #XX -- [ Pg.41 ]



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