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Acidity of carbonyl compounds

Mechanism The protonation of C=0 bond with acid of carbonyl compound leads to A, which undergoes a nucleophilic attack by peroxy acid. The migration of one alkyl group to electropositive oxygen and elimination of carboxylate from perester B gives the protonated ester C. Finally, the base takes a proton from C and ester is formed (Scheme 7.17). [Pg.286]

Aldehyde or ketone Hydronium ion Conjugate acid of carbonyl compound Water... [Pg.739]

See other pages where Acidity of carbonyl compounds is mentioned: [Pg.718] [Pg.718] [Pg.760] [Pg.760] [Pg.760] [Pg.760] [Pg.736] [Pg.263] [Pg.1079] [Pg.411] [Pg.413] [Pg.18] [Pg.666] [Pg.666] [Pg.706] [Pg.706] [Pg.17] [Pg.666] [Pg.666] [Pg.706] [Pg.706] [Pg.739] [Pg.899] [Pg.1075] [Pg.700] [Pg.895]

See also in sourсe #XX -- [ Pg.417 , Pg.420 ]

See also in sourсe #XX -- [ Pg.18 ]

See also in sourсe #XX -- [ Pg.591 , Pg.597 ]

See also in sourсe #XX -- [ Pg.17 ]

See also in sourсe #XX -- [ Pg.595 ]

See also in sourсe #XX -- [ Pg.417 , Pg.418 , Pg.419 ]

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Acidic carbonyl

Acidity constants of simple carbonyl compounds

Addition of hydrocyanic acid to carbonyl compounds