Acetylation veneers

It is of interest that veneer-faced low-density particleboards made from acetylated veneers and acetylated core particles showed excellent dimensional stability in both liquid water and humidity tests and were resistant to attack by fungi in an 8-week soil block test [57]. Furthermore, during the 150-day bending-creep test, the totally acetylated boards showed no strength or weight loss during exposure to T. palustris. 

Rowell, R.M., Imamura, Y., Kawai, S. and Norimoto, M. (1989). Dimensional stability, decay resistance, and mechanical properties of veneer-faced low-density particleboards made from acetylated wood. Wood and Fiber Science, 21(1), 67-79. 

Acetylation of cellulose to the triacetate has been carried out without breaking down of the structure with acetic anhydride containing pyridine to help open up the cell wall structure and to act as a catalyst (71). This led Stamm and Tarkow (72) to test the liquid phase reaction on wood. High dimensional stabilization without break down of the structure was obtained, but excessive amounts of chemical were used. They hence devised a vapor phase method at atmospheric pressure that proved suitable for treating veneer up to thicknesses of 1/8 inch. Acetic anhydride pyridine vapors generated by heating an 80-20% mixture of the liquids were circulated around sheets of veneer suspended in a box lined with sheet stainless steel. Hardwood veneer,... 

Acetylation can also be done by vapor-phase treatments, but the diffusion rate varies inversely as the square of the thickness (37, 56). Because of this effect, vapor-phase treatment has been applied only to thin veneers. 

USDA, Forest Service, Forest Products Laboratory, FPL GTR-55 Rowell RM, Imamura Y, Kowai S and Norimoto M (1989) Dimensional stability, decay resistance and mechanical properties of veneer faced low-density particlehoards made from acetylated wood. Wood and Fiber Science, 27(1)67-79 Rowell RM, Kawai S and Inone M (1995) Dimensionally stabilized, very low density fibreboard. Wood and Fiber Science, 27(4) 428-36 Rozsa AN (1994) Dielectric vacuum drying of hardwood. Proceedings 4th lUFRO International Drying Conference, Rotorua, New Zealand, 271-8 Ruddick JNR (1987) Proceeding of the incising workshop, Richmond, British Colombia, 1986. Special Publication 28. Forinteck Canada Corp., Vancouver, BC... 

Acetylation Hydroxyl groups reacted to form esters Acetic anhydride with pyridine catalyst and swelling agent in gas phase capillaries empty ASE about 70% (acetyl 25 %) Thin veneers to 2 X 6 X 48 in. stock... 

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