Acetophenone Acetylacetone

Acetone Cyanohydrin Acetonitrile Acetophenone Acetylacetone Acetylbenzene Acetyl Bromide Acetyl Chloride Acetylene... 

Krivun, Shian, and Dorofeenko condensed acetylacetone or dibenzoylmethane with various ketones (acetone, acetophenone, acetothienone, 1-acetylnaphthalene, or 5-acetylacetaphthene) and obtained pyrylium salts in 10-20% yield in the presence of perchloric acid. 

The Michael reaction of benzylidene acetophenone and benzylidene acetone with ethyl acetoacetate, nitromethane, and acetylacetone was studied by Musaliar and co-workers in the presence of a cetyltrimethy-lammonium bromide-containing aqueous micellar medium.50 The Michael reaction of various nitro alkanes with electrophilic alkenes is performed in NaOH (0.025-0.1 M) in the presence of cetyltrimethylam-monium chloride (CTACI) without any organic solvent (Eq. 10.23).51... 

Ru(acac)(bpy)3](PFg) is made from RuCl Cbpy), acetylacetone and (NH )PFg. It is dark brown IR and electronic spectra, TGA and cyclic voltammetry were measured. As [Ru(acac)(bpy)2]" /TBHP/CH3Cl2 it oxidised primary alcohols to aldehydes, secondary alcohols to ketones, di-tert-butylcatechol to the o-benzoqui-none and alkanes to ketones, e. g. ethylbenzene was converted to acetophenone and fluorene to fluorenone [787],... 

The tendency for antimony to achieve CN six is shown by the behaviour of organohaloantimony(V) compounds to substitution by oxo ligands. Jha et al.93 have employed the bidentate ligands acetylacetone, 8-hydroxyquinoline, salicylaldehyde, o-hydroxy-acetophenone and 2-hydroxynaphthaldehyde HL (equation 22). 

Acetonitrile, 407 Acetophenone, 725,729,730 phenylhydrazone, 852 p-Acetotoluidide, 593, 605 Acetoxime, 343 Acetylacetone, 861, 862, 863 Acetylation, reductive, 749 Thiele, 749 Acetyl chloride, 367 2-Acetylcyciohexanone, 862, 864 Acetylene, 245, 897 reactions of, 245, 246 Acetylenic compounds, synthesis of, 467-469, 895-902 Acetylglycine, 909 Acetylmethylurea, 968, 969 Acetylsalicylio acid, 996 Acetyl-o-toluidide, 578 2-Acetylthiophene, 837 Acid anhydrides of aliphatic carboxylic acids, 371... 

Acetophenone, A/-methyloxazolidine derivative, lithiation, 56, 261 Acetyl hypofluorite fluorination of uracil by, 59, 3 fluorination using, 60, 7 reaction with pyridines, 58, 280, 289 Acetylacetone, hexafluoro-, reaction with ethylenediamine, 56, 3 Acetylene cyclic dimer, trimer. tetramer, dissociation energies, 56, 343 Acetylenes, activated reactions with 3-diazo-azoles, 59, 70... 

---