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Acetate carborane anions

Lead(II) acetate can be used as an alternative to lead(II) halides with carborane anions, offering advantages in solubility in certain systems. [Pg.393]

Synthesis of unsubstituted mercuracarborands, as illustrated in Scheme 1, is a two-step process involving deprotonation of the acidic CH vertices of 1,2-carborane 7 followed by treatment with the appropriate mercury salt <1994JA7142, 1997ACR267>. Thus, -butyllithium efficiently deprotonates 1,2-carborane 7 giving doso-X.Z-VXz-1,2-C2BioHio 8, the pivotal intermediate. If treated with mercury acetate, neutral trimer 5 is formed. Using mercury chloride or bromide, however, leads to the formation of tetramer 9 and 10, respectively, as 1 1 anion-host complexes. [Pg.1053]

See other pages where Acetate carborane anions is mentioned: [Pg.393]    [Pg.393]    [Pg.394]    [Pg.394]    [Pg.235]    [Pg.120]    [Pg.1055]    [Pg.210]    [Pg.365]    [Pg.210]    [Pg.230]    [Pg.685]   
See also in sourсe #XX -- [ Pg.3 , Pg.4 , Pg.5 , Pg.10 , Pg.22 ]

See also in sourсe #XX -- [ Pg.3 , Pg.4 , Pg.5 , Pg.22 ]



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Acetate anion

Carboran

Carboranate

Carboranate anion

Carborane anions

Carboranes

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