4-Acetamido-phenol

TrinitTO 4-acetamidophenol, CHaCO.-NH. CeHfNOj),. OH, It brn scales (from AcOH), mp I9l-2ctdec), easily sol in ale AcOH, Can be prepd by treating 3,5-dit itro-4-acetamido-phenol with fuming nitric acid at0°or by other methods. Its explosive props were not examined Refs l)Beil 13,(195) 2)F. Reverdin ... 

Scheme 1 Hydrolysis of diphenyl-carbonate (1) to give 4-nitro-phenol (2), 4-acetamido-phenol and carbon dioxide. The diphenyl-phosphate (4) was used as TSA to mimic the tetrahedral transition state formed during the hydrolysis...

Can be prepd by treating 2,3,6-tritro-acetamido-phenol with Na azide in warm w. Its expl props were not examined... 

Azidoacetamidophenol. See under Acetamido-phenol and Derivatives, p A20 21 Azidoacetamidophenol, Dinitro. See under Acetamidophenol and Derivatives, p A21... 

Oxazolium salts are easily attacked by nucleophiles. The hydrolysis of oxazoles and benzoxazoles by hydrochloric acid has long been known. Triphenyloxazole gives benzoic acid, benzaldehyde and ammonium chloride 2-methylbenzoxazole affords o-acetamido-phenol, and 5-ethoxy-2-pentyloxazole is rapidly converted into the acylamino ester (132) by dilute hydrochloric acid at room temperature (Scheme 4). 

Acetamido-4-amino-6-chloro-s-triazine, see Atrazine Acetanilide, see Aniline, Chlorobenzene, Vinclozolin Acetic acid, see Acenaphthene, Acetaldehyde, Acetic anhydride. Acetone, Acetonitrile, Acrolein, Acrylonitrile, Aldicarb. Amyl acetate, sec-Amyl acetate, Bis(2-ethylhexyl) phthalate. Butyl acetate, sec-Butyl acetate, ferf-Butyl acetate, 2-Chlorophenol, Diazinon. 2,4-Dimethylphenol, 2,4-Dinitrophenol, 2,4-Dinitrotoluene, 1,4-Dioxane, 1,2-Diphenylhydrazine, Esfenvalerate. Ethyl acetate, Flucvthrinate. Formic acid, sec-Hexyl acetate. Isopropyl acetate, Isoamyl acetate. Isobutyl acetate, Methanol. Methyl acetate. 2-Methvl-2-butene. Methyl ferf-butvl ether. Methyl cellosolve acetate. 2-Methvlphenol. Methomvl. 4-Nitrophenol, Pentachlorophenol, Phenol. Propyl acetate. 1,1,1-Trichloroethane, Vinyl acetate. Vinyl chloride Acetoacetic acid, see Mevinphos Acetone, see Acrolein. Acrylonitrile. Atrazine. Butane. 

Aryl glycosides of 2-amino-2-deoxy sugars, as might be expected, can be prepared by similar techniques as was illustrated by the synthesis of phenyl 3,4,6-tri-0-acetyl-2-acetamido-2-deoxy-p-D-glucoside and -D-galactoside by toluene -sulphonic acid catalysed reactions between phenol and the hexosamine penta-acetates These products were then anomerised using zinc chloride as catalyst to provide means of obtaining -anomers. 

C14H18N208 2 -nitrophenyl-2-acetamido-2-deoxy-a-D-gluco 10139-01-2 25 00 1 3448 2 27688 C14H220 tert-octyl phenol 27193-28-8 25.00 0.9410 1... 

C14H18N208 4-nitrophenyl-2-acetamido-2-deoxy-b-D-glucop 3459-18-5 25.00 1.3448 2 27691 C14H220 2-isopropyl-6-(1-methyl butyl)phenol 74926-98-0 21.20 0.9389 2... 

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