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6,6a-Dehydroglaucine

The dehydrogenation of 66 to 6a,7-dehydroglaucine (79) proceeded in a yield of 60% with Fusarium solani ATCC 12823. This microorganism also produced a 21% yield of the oxoaporphine 80, but control experiments indicated that the latter was an artifact produced by air oxidation of 79 during the incubation. [Pg.360]

The constitutions of 6a,7-dehydroglaucine (26e) (191), hernandonine (35c) (432), imenine (35e) (433), oxonuciferine (35g), dicentrinone (35h), and lanuginosine (35b) have been elucidated (393, 434). The latter five oxo bases have not yet been found in the Papaveraceae. Because some of the oxo-aporphine alkaloids have cytotoxic (tumor inhibiting) properties, their further study could be fruitful (435). [Pg.414]

See other pages where 6,6a-Dehydroglaucine is mentioned: [Pg.381]    [Pg.350]    [Pg.350]    [Pg.351]    [Pg.351]    [Pg.359]    [Pg.381]    [Pg.350]    [Pg.350]    [Pg.351]    [Pg.351]    [Pg.359]    [Pg.967]    [Pg.411]    [Pg.8]    [Pg.75]   
See also in sourсe #XX -- [ Pg.350 , Pg.351 , Pg.359 , Pg.360 ]



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