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Directed Aldol Additions

Directed aldol condensation using ATPH

Directed Aldol Condensations

Directed alumination of alkoxy-substituted aromatics and heteroaromatics

Directed alumination of aromatics using the sterically hindered Al-base 69

Directed arylation via C-C 0 bond cieavage.

Directed assembly of particles. Huorescent and nonfluorescent particles betir complementary strands of DNA. Particles are moved in contact to promote hybridization between the DNA strands and form the following rigid structures

Directed assembly of unprecedentedly large chiral metallocycles.

Directed C-H alkylation of cyclopropanes.

Directed C-H alkylation with organoboron reagents.

Directed C-H alkynylation of ort io-vinyl phenols

Directed clipping. The directed synthesis of -rotaxane 20 by cyclization of the key intermediate 16.

Directed combinatorial chemistry usingchemoenzymatically synthesized oligosaccharide building blocks.

Directed couplings of 1,3-enynes

Directed cross coupling at the benzylic position of benzyl amine

Directed dilution ventilation

Directed evolution applied to enzymes for the production of atorvastatin synthesis intermediates. The substrates and products of the evolved enzymes are shown

Directed evolution of a cyclohexanone monooxygenase for the asymmetric sulfoxidation of a prochiral thioether.

Directed evolution of a cyclohexanone monooxygenase for the oxidative des5mimetrization of 4-hydroxycyclohexanone.

Directed evolution of an enantioselective enzyme ,

Directed evolution of cyclohexanone monooxygenases improves enantioselectivety in Baeyer-Villiger reactions.

Directed evolution of enzymes - the general method.

Directed evolution of hybrid catalysts comprising mutants of streptavidin 36, the Rh-catalyzed hydrogenation 37— 38 serving as the model reaction

Directed evolution of hybrid catalysts.123,124

Directed evolution of KDPGal aldolase for application to whole-cell production of 3-dehydroshikimate



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