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Ruthenium-catalyzed 1,4-addition of organoboronic adds to a,p-unsaturated ketones, as described by Shintani and Hayashi .

Ruthenium-catalyzed acylation of arenes

Ruthenium-catalyzed addition of alkenesulfonyl chlorides.

Ruthenium-catalyzed addition of allyl alcohol to phenylacetylene.

Ruthenium-catalyzed addition of allyl alcohol to terminal alkynes with skeleton rearrangement.

Ruthenium-catalyzed addition of carboxylic acids to olefins

Ruthenium-catalyzed addition of carboxylic acids to propargylic alcohols

Ruthenium-catalyzed aerobic oxidation of amines using a coupled catalytic system.

Ruthenium-catalyzed alkylation of ketone 20

Ruthenium-catalyzed alkylation of phenol

Ruthenium-catalyzed amidation of benzylic alcohol. X describes the substrates used in the Hammett study.

Ruthenium-catalyzed anti-Markovnikov addition of amides to alkynes

Ruthenium-catalyzed anti-Markovnikov hydroamination of styrene.

Ruthenium-catalyzed arylation of ketone 36 in pinacolone

Ruthenium-catalyzed arylation of the aldimine 55.

Ruthenium-catalyzed atom transfer radical cyclizations

Ruthenium-catalyzed C-C coupling of diols with aUcynes via transfer hydrogenation. Yields are of material isolated by flash chromatography on silica gel. C10H15CO2H 1-adamantanecarboxylic acid. PCys tricyclohexylphosphine

Ruthenium-catalyzed C-C coupling of primary alcohols with 1,3-dienes to form homoallylic alcohols or P.y-enones. Yields are of material isolated by flash chromatography on silica gel.

Ruthenium-catalyzed C-H acetylene coupling.

Ruthenium-catalyzed C-H animation reactions

Ruthenium-catalyzed carbonylation of amides

Ruthenium-catalyzed carbonylative C-H activations

Ruthenium-catalyzed carbonylative reaction of cyclopropyl imines.

Ruthenium-catalyzed carbonylative synthesis of hydroquinones.

Ruthenium-catalyzed carbonylative synthesis of maleimides.



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