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In an M4L6 tetrahedron tris-bidentate chelation of octahedral metal centers generates C3 axes, while the bis-bidentate ligands provide C2 axes. Precise arrangement of these symmetry axes is required for

In an octahedral complex with six 7r-donor or acceptor ligands lying on the x, y and r axes, each ligand provides two tt-orbitals, e.g. for ligands on the x axis, bothpy andp orbitals

In an octahedral complex with six 7r-donor or acceptor ligands lying on the X, y and z axes, each ligand provides two 7r-orbitals, e.g. for ligands on the x axis, both py and orbitals are available

In an octahedral complex with six tt-donor or -acceptor ligands lying on the x, y and z axes, each ligand provides two 7r-orbitals, e.g. for ligands on the x axis, both Py and orbitals are available for rr-bonding. Now consider just one plane containing four ligands of the octahedral complex, e.g. the xz plane. Diagram shows the antibonding combination.

In an oH-in-water-in-oil emulsion the water droplets in the oil phase themselves contain oil droplets.

In an oil-in-water-in-oil emulsion the water droplets in the oil phase themselves contain oil droplets.

In an overloaded toughened adhesive, crack propagation is stopped by the dispersed rubbery phase.

In an SmC film, a 2k disclination is induced by anchoring conditions at the edges of the film.

In an umbrella sampling simulation for pathways configuration space is covered with a sequence of overlapping windows W. For each window a separate transition path sampling simulation for paths with starting points in A and endpoints in V is carried out. From the order parameter distributions matched where the windows overlap the distribution PA X,t can be calculated

In an w-to--ir transition of a carbonyl group, an electron in a nonbonding orbital is excited into an antibonding tt orbital spread over both atoms.

In analogue of the aromatic cyclopropenyl cation , This delocalized bishomocyclopropenyl structure for 7-norbomenyl cations has been controversial, but is supported by NMR studies .

In analogy with Example 21.5, the multivariate control limits define the dark, ellipsoidal region that represents in-control behavior. Figure 21.9 demonstrates that the application of univariate SPC techniques to correlated multivariate data can result in two types of misclassification

In analytical chemistry, heteroskedasticity is mostly present as an increase in variance at higher concentration levels.

In another case the exploration is performed lateral to the Sylvian

In any case, the surface elemental EDAX analysis indicates that NiO is the predominant species at the TLC surface, whereas only a trace amoimt of Si on the surface of the N4-TLC sample has been detected.

In any cyclic process during which a system is restored to its initial state, the increase in the internal energy of the system is AU 0.

In AOTj benzene microemulsions , the signal associated with the H2 proton of C mimj appears at 5 9.356ppm, which is 0.895 ppm shifted downfield compared to neat TF2Nj. This huge downfield shift is well supported by many other studies and confirms the incorporation of IL inside the RM . With further addition of IL, , that is, with increasing R value from 0.2 to 1.0, the peaks associated with the H2 proton of and H2 proton of gets shifted upheld from 9.150 and 9.239 ppm to 8.754 and 8.858 ppm, respectively

In applications where it is important to consider resolution, the data in

In apV diagram the adiabats have a steeper course than isotherms the reason is that the temperature T changes in the adiabatic process and thus influences the pressure p in the gas.

In aqueous electrolytes, the potential window observed for diamond electrodes is wider than that for the other carbon-based electrodes. In non-aqueous electrolytes, however, those values are very similar to those reported for the other carbon-based electrodes .

In aqueous solution, a sulfo-NHS ester can either couple to an amine group to form an amide bond or reaa with water to hydrolyze back to a carboxylate. Both processes release the sulfo-NHS leaving group.

In aqueous solution, a sulfo-NHS ester can either couple to an amine group to form an amide bond or react with water to hydrolyze back to a carboxylate. Both processes release the sulfo-NHS leaving group.

In aqueous solution, these two forms interconvert rapidly via the open-chain glucose form and cannot be separated. They can be isolated separately in crystalline form, however. D-fructose, a common sugar found in fruit and honey, has the same molecular formula as D-glucose but is a member of a class of hexose sugars that are ketones rather than aldehydes. In their straight-chain forms, these sugars have the C 0 bond at carbon atom 2 rather than carbon atom 1

In aqueous solutions of crystallizable CDs. depending on their concentrations, the solubility of poorly soluble compounds is increased. When reaching the solubility limit of the formed inclusion complex, the concentration dissolved drug reaches a plateau or even drops back. In the case of non-crystallizable CD derivatives, no such limit is attained, therefore, to form practically water-insoluble steroid. 10 or 20 or even more mg substances can be dissolved in the 1 ml solution of an appropriate CD derivative.

In ared spectra of poly 2,3-ciiaceto



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