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Y-Oximino alcohol

Conversion of a nitrite ester to a y-oximino alcohol by photolysis involving the homolytic cleavage of a nitrogen-oxygen bond followed by hydrogen abstraction ... [Pg.84]

Selective reduction of the oximino fragment in products (224) or (225) gives rise to poorly studied y-amino alcohols (226). In addition, desoximation of (225) can produce the corresponding p-hydroxycarbonyl derivatives (227). In addition, oximino alcohols (225) can be oxidized to y-nitro alcohols (228). [Pg.572]

Ethyl 2-amino-a-oximino-4-pyrimidinepropionate obtained from 2-amino-4-methyl-pyrimidine and ethyl oxalate in the presence of 2 moles K-ethoxide and treatment of the intermediate (Y 70%) with 2 equivalents hydroxylamine in aq. alcohol (Y 75%) allowed to react with SnClg in aq. HCl -> DL-lathyrine (Y 55%). Y. P. Shvachkin and G. A. Korshunova, Vestn. Mosk. Univ., Khim. 23 (3), 105 (1968) C. A. 70, 4571. [Pg.19]

See other pages where Y-Oximino alcohol is mentioned: [Pg.32]    [Pg.127]    [Pg.26]    [Pg.24]    [Pg.26]    [Pg.32]    [Pg.127]    [Pg.26]    [Pg.24]    [Pg.26]    [Pg.167]    [Pg.95]   
See also in sourсe #XX -- [ Pg.32 ]

See also in sourсe #XX -- [ Pg.26 ]

See also in sourсe #XX -- [ Pg.30 ]

See also in sourсe #XX -- [ Pg.24 ]

See also in sourсe #XX -- [ Pg.26 ]



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