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Xanthate complexes iron structures

As with earlier sections, there is a lack of structural data on binary xanthates for iron, ruthenium, and osmium, but there are a relatively large number of mixed-ligand complexes, particularly organometallic species. [Pg.156]

A number of iron(III) xanthates and thioxanthates have been prepared (1). The structure of the predominantly low-spin [Fe(Rxant)a] (R = Et, or SBu) complexes show features (246, 252) of coordination about the iron atom that are significantly different from those of [Fe(Bu2dtc>3], and it is estimated that there is 10-30% of double-bond character in coordinated S2CX (X = OR, or SR), which is appreciably... [Pg.241]

See other pages where Xanthate complexes iron structures is mentioned: [Pg.240]    [Pg.156]    [Pg.240]    [Pg.149]    [Pg.150]    [Pg.364]   
See also in sourсe #XX -- [ Pg.156 , Pg.157 ]



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