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Wolff rearrangement stereochemistry

The synthesis of the skeleton of these two monoterpenic alkaloids and the control of the relative stereochemistry at C4, CS, and C6 was aehieved using a Wolff rearrangement followed by a photoreductive cyclization of unsaturated Af-alkyl-2-oxo-cyclopentane carboxamides of type D (Scheme 40). [Pg.173]

See other pages where Wolff rearrangement stereochemistry is mentioned: [Pg.101]    [Pg.101]    [Pg.265]    [Pg.268]    [Pg.712]    [Pg.617]    [Pg.624]    [Pg.460]    [Pg.494]    [Pg.147]    [Pg.345]    [Pg.112]    [Pg.492]    [Pg.52]   
See also in sourсe #XX -- [ Pg.891 ]



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Rearrangements Wolff rearrangement

Stereochemistry rearrangements

Wolff

Wolff rearrangement

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