With thiazolyl carbamates

Use of aprotic solvents increases the quantity of exocyclic N-alkylation the potassium salt of N-(2-thiazolyl)carbamate heated in DMF with 2-phthalimidoethyl bromide gives predominantly exocvclic N-alkylation (70% 47a, 30% 47b) (Scheme 34) (131). 

Ethyl-N-(2-thiazolyl)carbamate reacts with aqueous hydrazine to give 271 (Scheme 165) (263). 

The 2-imino-4-thiazolines may be used as ultraviolet-light stabilizers of polyolefin compositions (1026). 2-Aminothiazole improves adhesive properties of wood to wood glue (271). Cbmpound 428 exhibits antioxidant properties (Scheme 242) (1027). Ammonium N-(2-thiazolyl)dithio-carbamate (429) is a bactericide and fungicide used in industrial products such as lumber, paint, plastics, and textiles (1037). Compound 430 is reported (1038) to form an excellent volume of foam coating in aluminum pans when ignited with propane. 

The acetyl group of 10-ace tyl-9-fluoro-3-methyl-7-oxo-2,3-dihydro-7//-pyrido[l,2,3-de]-l,4-benzoxazine-6-carboxylic acid was brominated with KBr03 and 48% HBr acid in AcOH, and the 2-bromoacetyl group was then converted into a 10-[2-aminomethyl-4-thiazolyl] group with phenylmethyl (2-amino-2-thioxoethyl)carbamate and subsequent treatment with 32% HBr (87JHC1509). 

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