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Winkler-Dunitz distortion parameters

Amide distortion parameters defined in accordance with Winkler-Dunitz . [Pg.849]

Angle subtended by the axes of the nitrogen lone pair and the carbonyl carbon 2p orbital. Amide distortion parameters defined in accordance with Winkler-Dunitz . [Pg.869]

It was mentioned above that the 4.3.3 lactams appear to represent a resonance maximum for the BBL series. It might be better to think of them as a distortion minimum. Certainly, their Winkler and Dunitz parameters are smallest for all of the BBLs in the series. While one might logically predict that making the bridges larger would allow fir more freedom of motion and consequently... [Pg.332]


See other pages where Winkler-Dunitz distortion parameters is mentioned: [Pg.848]    [Pg.848]    [Pg.45]    [Pg.868]    [Pg.323]   
See also in sourсe #XX -- [ Pg.848 , Pg.867 , Pg.868 , Pg.869 , Pg.899 , Pg.900 , Pg.917 ]




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Distortion parameter

Dunitz

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