Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Why does crystallization of a solute occur

Atoms or ions of solute leave solution during the process of crystallization to form a regular repeat lattice. [Pg.137]

The extent of solute disorder is high before crystallization, because each ion or molecule resides in solution, and thereby experiences the same freedom as a molecule of liquid. Conversely, the extent of disorder after crystallization will inevitably be much smaller, since solute is incorporated within a solid comprising a regular repeat lattice. [Pg.137]

The value of AS can only be negative because the symbol A means final state minus initial state , and the extent of disorder during crystallization clearly follows the order solute disorder(initiai) solute disordering) . We see how the extent of disorder in the solute decreases during crystallization in consequence of forming a lattice and, therefore, do not expect crystallization to be a spontaneous process. [Pg.137]

But crystallization does occur, causing us to ask, Why does crystallization occur even though AS for the process is negative  [Pg.137]

To answer this question, we must consider all energetic considerations occurring during the process of crystallization, possibly including phenomena not directly related to the actual processes inside the beaker. [Pg.137]


See other pages where Why does crystallization of a solute occur is mentioned: [Pg.137]   


SEARCH



Crystallization of solutes

Crystallization solute

Solution Crystallized

© 2024 chempedia.info